Nat Wolff steps out for the premiere of Peace, Love & Misunderstanding held at Roy Thomson Hall during the 2011 Toronto International Film Festival on Tuesday (September 13) in Toronto.

The 16-year-old actor plays Jake in the flick, opposite Chace Crawford, Jeffrey Dean Morgan and Elizabeth Olsen.

Peace, Love & Misunderstanding follows an uptight NYC lawyer who takes her two teenagers to her hippie mother’s farmhouse upstate for a family vacation.

You’ll also see Nat in the upcoming New Year’s Eve as Walter.

10+ pics inside of Nat Wolff…