Dean hits the stage and shows off his vocal chops in this still from tonight’s new Supernatural.

In “Last Call”, Dean (Jensen Ackles) goes off on his own to take on a case and ends up performing a duet with Christian Kane!

Meanwhile, Castiel (Misha Collins) has an idea of how he can help Sam (Jared Padalecki) track down God.

Check out a sneak peek and stills from tonight’s Supernatural below, airing Thursday, December 5th @ 8PM ET/PT on The CW.

Psst, if you didn’t know, Jensen actually just released a full album!